Studying the dynamic performance of rocks affected by high temperatures is a crucial theoretical foundation of mining engineering design and the construction of deep metallic mineral resources. More importantly, such studies can provide technical support for the green and low-carbon mining of these resources. However, systematic studies on the dynamic mechanical properties of rocks affected by both confining pressure and temperature during the mining of deep metallic mineral resources are lacking. Therefore, systematic research was conducted on the dynamic mechanical properties of limestone under confining pressure after high-temperature treatment, and a corresponding constitutive model was established. In this study, limestones were heated to 200 °C, 400 °C, 600 °C, and 800 °C, and the Split Hopkinson Pressure Bar impact test was conducted with confining pressures of 0.0 MPa, 0.5 MPa, 1.5 MPa, and 2.5 MPa. The test results show that the temperature has a significant effect on the dynamic compressive strength of limestone, and as the temperature rises, the strength tends to first increase and then decrease, reaching the turning point at a temperature of 400 °C. The dynamic compressive strength increases as the confining pressure increases. The constitutive equation of the dynamic damage to limestone under confining pressure after high-temperature treatment is consistent with the test results. Therefore, the established constitutive model can represent the dynamic behavior of limestone, providing a reference for evaluating the dynamic performance of this material, and serving as a theoretical basis for the green and low-carbon mining of deep metallic mineral resources.