We study the dust surface potential for the complex dusty plasma with negative ions and with a three-parameter non-Maxwell velocity distribution. The plasma contains electrons, positive ions, negative ions, and negatively charged dust particles. By using the current equilibrium condition, we derive the relationship between the normalized dust surface potential and the dusty plasma parameters such as the normalized dust number density, the temperature ratio of negative ions to electrons, the density ratio of negative ions to positive ions, and the charge number of negative ions. The numerical analyses show that the relationship depends evidently on the three parameters in the non-Maxwell distribution when the dust surface potential is relatively smaller, but with increase of the potential, such dependence will weaken soon. The dust surface potential is negative and increases monotonously with increase of the dust density, and for the complex dusty plasma with the three-parameter non-Maxwell distribution, it is generally greater than that in the same plasma with the kappa-distribution and the Maxwellian distribution.Introduction. -Dust particles are some of solid grain matter common in the universe, while gaseous matter in astrophysical and space systems is often in the fully ionized or partially ionized plasma state. In this way, the plasma as well as the dust particles immersed in it constitutes a complex dusty plasma system. It is complex system because, in addition to the conventional electron-ion plasma, additional components such as neutral gas molecules, negative ions, and dust particles of large mass (relative to ions) or nebula clusters are added to the plasma system. Dusty plasmas exist in different parts of the cosmic environments such as interstellar medium, planetary rings, phobos-dust rings, comet tails and interstellar molecular clouds. At the same time, they also exist in the fusion reactors and the plasma processing industrial installations [1][2][3][4]. Plasma containing dust particles can be regarded as dusts in plasma or dusty plasma, which depends on some characteristic lengths such as the dusty particle radius r d and the average distance a between particles (related to dust number density n d , n d a 3 ~1). If Debye radius is λ D and when there is r d << a <λ D , that is, charged dust particles participate in the collective behavior, corresponding to the dusty plasma. When there is r d << λ D < a, that is, charged dust particles are