“…Recently, LMSs as a novel 2D material, including SnS 2 [28], TiS 2 [29], SnSe 2 [18,30], TiSe 2 [31], In 2 Se 3 [32], Sb 2 S 3 [33,34], etc, were found to possess many outstanding optical and photonic properties, such as a broad band response wavelength range of linear optical absorption, an ultrafast relaxation time and recovery time, a large modulation depth, a high damage threshold, Pauli blocking-induced saturable absorption, strong saturation intensity and high optical nonlinearity, so they have been widely used as SAs in fiber and solid-state lasers. Antimony sulfide (Sb 2 S 3 ), as a novel LMS, with an orthorhombic structure consisting of ribbon-like chains of parallel molecular (Sb 4 S 6 ) n [35], possesses outstanding physical and optical properties, including exotic photoconductive effect, high Seebeck coefficient, high absorption coefficient, etc [36,37].…”