We realize mirror templates on the tips of optical fibers using a single-shot CO 2 laser ablation procedure. We perform a systematic study of the influence of the pulse power, pulse duration, and laser spot size on the radius of curvature, depth, and diameter of the mirror templates. We find that these geometrical characteristics can be tuned to a larger extent than has been previously reported, and notably observe that compound convex-concave shapes can be obtained. This detailed investigation should help further the understanding of the physics of CO 2 laser ablation processes and help improve current models. We additionally identify regimes of ablation parameters that lead to mirror templates with favorable geometries for use in cavity quantum electrodynamics and optomechanics.