Abstract:N,N’‐Diaryl ethylenediamines are common feedstocks in organic synthesis and important structural motifs in medicinal chemistry. Whereas the C−N formation reactions based on anilines and aryl halides are the most direct methods to access N,N’‐diaryl ethylenediamines, the photocatalytic synthetic version remains undeveloped. Herein we describe the dual nickel/photoredox‐catalyzed amination reaction using nitroarenes and trimethylamine as reaction substrates. This cascade transformation hinges on the multiple C−N… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.