Dual-end-functionalized tin (Sn)-phyllosilicates for the esterification of oleic acid

Nam, Bora; Lee, Hyun Uk; Park, So Young; Son, Byung-Chul; Lee, Go-Woon; Park, Jiyeon; Lee, Young-Chul

doi:10.1016/j.jiec.2016.07.002

Cited by 5 publications

(1 citation statement)

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“…Structural diversity, compatibility with various transition metals, high surface area, and finely dispersed metallic cations makes phyllosilicates attractive in numerous reactions, such as Fischer-Tropsch [43], esterification [44], cellulose conversion to glucose [45], oxidation of water [46,47], oxidation of CO [48][49][50][51][52], CO or CO2 reforming [34,[53][54][55][56][57][58][59][60][61], hydrogen generation from methanol steam reforming [62][63][64][65][66], and syntheses of valuable alcohols from hydrogenation of CO [67][68][69], CO2 [53,[70][71][72], and hydrogenolysis of esters [73][74][75][76][77][78][79][80][81][82][83][84][85][86]...…”

Section: Introductionmentioning

confidence: 99%

Copper Phyllosilicates-Derived Catalysts in the Production of Alcohols from Hydrogenation of Carboxylates, Carboxylic Acids, Carbonates, Formyls, and CO2: A Review

Lin

2021

Catalysts

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Copper phyllosilicates-derived catalysts (CuPS-cats) have been intensively explored in the past two decades due to their promising activity in carbonyls hydrogenation. However, CuPS-cats have not been completely reviewed. This paper focuses on the aspects concerning CuPS-cats from synthesis methods, effects of preparation conditions, and dopant to catalytic applications of CuPS-cats. The applications of CuPS-cats include the hydrogenation of carboxylates, carboxylic acids, carbonates, formyls, and CO2 to their respective alcohols. Besides, important factors such as the Cu dispersion, Cu+ and Cu0 surface area, particles size, interaction between Cu and supports and dopants, morphologies, and spatial effect on catalytic performance of CuPS-cats are discussed. The deactivation and remedial actions to improve the stability of CuPS-cats are summarized. It ends up with the challenges and prospective by using this type of catalyst.

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