Abstract:So far, the earlier reported strong correlation between basicity of an N-heterocyclic carbene (NHC) and its reactivity in poly(ε-caprolactam) (PA6) synthesis resulted in a substantial limitation of applicable carbenes. Here, to overcome this issue, 1,3-dimethylimidazolium-2-carboxylate, an easily accessible, air and moisture-stable NHC, was applied as thermally latent initiator. In order to compensate for its low basicity, reactivity was enhanced by the addition of both a Lewis acid and an activator to ease th… Show more
This review highlights recent developments in nylon polymer synthesis techniques, novel monomer structures developed, and biomedical applications of nylon polymers.
This review highlights recent developments in nylon polymer synthesis techniques, novel monomer structures developed, and biomedical applications of nylon polymers.
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