Dual activity of durable chiral hydroxyl-rich MOF for asymmetric catalytic reactions

High performance of ultrasonic-assisted synthesis of two spherical polymers for enantioselective catalysis

“…In contrast to the above-mentioned strategies, using chiral external agent is a fast, low-cost and controllable pathway for chiralization of supramolecular especially metal–organic hybrid materials and chiral coordination polymers (CCPs) [19] , [20] , [21] , [22] , [23] , [24] . Until now, a lot of chiral catalysts have been successfully developed [25] , [26] , [27] such as polymer-supported chiral catalysts but lack of protection of chiral species is one of the disadvantages that it should be regarded. Since there are weaknesses in these catalytic systems such as leaching and decreasing of catalysts activity than their homogeneous counterparts.…”

Complete and Versatile Post‐Synthetic Modification on Iron‐Triazole Spin Crossover Complexes: A Relevant Material Elaboration Method

“…In addition to the advantages on chemical transformations, PSM reactions can provide a template for the solid state structure, in other words, main features of solid-state structures present in the "parent" materials can be preserved in the functionalized material in contrast with direct methods. [2,26,27,36,37] Finally, Wang et al [2] demonstrated that the PSM method leads to a more homogeneous material when MOF are incorporated in polymers. Indeed, the authors explain this observation by an increase in compatibility between the MOF and the polymer due to the formation of chemical bonds between the two entities.…”

“…synthesized Ti‐MOF complexes and then associated them by the coordination of the amino functional group on the Ti‐MOF to transition metals such as Ni or Cu. In addition to the advantages on chemical transformations, PSM reactions can provide a template for the solid state structure, in other words, main features of solid‐state structures present in the “parent” materials can be preserved in the functionalized material in contrast with direct methods [2,26,27,36,37] . Finally, Wang et al [2] .…”

Influence of Hydrogen Bond Donating Sites in UiO‐66 Metal‐Organic Framework for Highly Regioselective Methanolysis of Epoxides

“…[1][2][3] Within a short span of time, porous MOFs have gained much attention in inorganic chemistry due to their unique properties like gas storage, [4] gas/ liquid separation, [5] chemical sensing, [6] molecular magnetism, [7] drug delivery, [8] biomedicine, [9] optoelectronics, [10] heat transformation process, [11] host for metal nanoparticles [12] and heterogeneous catalysis. [11,[13][14][15] Particularly, Zr-based MOFs have received wider attention among other MOFs mainly due to their exceptional features like high surface area, [16] high thermal and chemical stability, [17] low toxicity, [18] tunable pore size and shape, [19] surface functionality and incorporation of a variety of functional moieties in linker molecule. [20] The unsaturated metal centers can act as Lewis acidic (LA) sites as well as the inclusion of Lewis acidic or Brønsted acidic (BA) functional group in linker enhances the catalytic activity in heterogeneous catalysis.…”

“…Metal‐organic frameworks (MOFs) are composed of metal ions or clusters and organic linker molecules in a highly ordered manner resulting in three‐dimensional framework solids with well‐defined porous struture . Within a short span of time, porous MOFs have gained much attention in inorganic chemistry due to their unique properties like gas storage, gas/liquid separation, chemical sensing, molecular magnetism, drug delivery, biomedicine, optoelectronics, heat transformation process, host for metal nanoparticles and heterogeneous catalysis . Particularly, Zr‐based MOFs have received wider attention among other MOFs mainly due to their exceptional features like high surface area, high thermal and chemical stability, low toxicity, tunable pore size and shape, surface functionality and incorporation of a variety of functional moieties in linker molecule .…”