Droplet Spreading Characteristics on Ultra-Slippery Solid Hydrophilic Surfaces with Ultra-Low Contact Angle Hysteresis

Abstract

Dynamic interactions of the droplet impact on a solid surface are essential to many emerging applications, such as electronics cooling, ink-jet printing, water harvesting/collection, anti-frosting/icing, and microfluidic and biomedical device applications. Despite extensive studies on the kinematic features of the droplet impact on a surface over the last two decades, the spreading characteristics of the droplet impact on a solid hydrophilic surface with ultra-low contact angle hysteresis are unclear. This paper clarifies the specific role of the contact angle and contact angle hysteresis at each stage of the droplet impact and spreading process. The spreading characteristics of the droplet impact on an ultra-slippery hydrophilic solid surface are systematically compared with those on plain hydrophilic, hydroxylated hydrophilic, and plain hydrophobic surfaces. The results reveal that the maximum spreading factor (βmax) of impacting droplets is mainly dependent on the contact angle and We. βmax increases with the increase in We and the decrease in the contact angle. Low contact angle hysteresis can decrease the time required to reach the maximum spreading diameter and the time interval during which the maximum spreading diameter is maintained when the contact angles are similar. Moreover, the effect of the surface inclination angle on the spreading and slipping dynamics of impacting droplets is investigated. With the increase in the inclination angle and We, the gliding distance of the impacting droplet becomes longer. Ultra-low contact angle hysteresis enables an impacting droplet to slip continuously on the ultra-slippery hydrophilic surface without being pinned to the surface. The findings of this work not only show the important role of the surface wettability in droplet spreading characteristics but also present a pathway to controlling the dynamic interactions of impacting droplets with ultra-slippery hydrophilic surfaces.

Water-Droplet Impact and Sliding Behaviors on Slippery Surfaces with Various Weber Numbers and Surface Inclinations

“…The We number was controlled by the falling height (i.e., H) of the water droplet. Here, We = ρv 2 r/γ [30,42], where r is the droplet radius, ρ is the droplet density (1000 kg/m 3 ), γ is the water surface tension (72 mN/m), and v is the droplet impact speed. The impact velocities and We numbers corresponding to water droplets of different falling heights are shown in Table 1.…”

Anti-Icing Mechanism for a Novel Slippery Aluminum Stranded Conductor

“…The dimensionless Weber number ( We ) was used to synthesize these parameters. We = ρ v 2 r /γ w, , where r is the droplet radius, 1.1 mm, ρ is the droplet density (1000 kg m –3 ), γ w is the water surface tension (75.3 mN m –1 at 2 °C, 72.7 mN m –1 at 25 °C), and v is the droplet impact speed. When the H was 20 cm, the We numbers at 2 and 25 °C were 57 and 59, respectively.…”