Controlled ejection
of liquids at capillary scales is a ubiquitous
phenomenon associated with significant advances in, for instance,
molecular biology or material synthesis. In this work, we introduce
a high-throughput approach, which relies on a micromixing mechanism
to eject and fragment viscous liquids, for production of microfibers
from poly(vinyl alcohol) solutions. First, filaments were generated
pneumatically with a so-called flow-blurring atomizer and using liquid
flow rates of up to ∼1 L/min. Subsequently, the filaments were
ionized online by corona discharge and consecutively manipulated with
an electric field created by disc electrodes. Such charging of the
filaments and the effect of the electric field allowed for their ultrafast
elongation and diameter reduction from 150 μm down to fibers
of 500 nm, which after collection exhibited fabric-like texture. The
approach presented herein is a general procedure with potential for
scalability that, upon proper adaptation, may be extended to various
polymeric materials.