Dreikomponentenreaktionen. XVII. Endständig reaktive Oligooxyethylenstrukturen aus Alkenen, Chlor und O‐Nucleophilen und deren Umsetzung zu Oxathiaalkanen

Abstract

Three Component Reactions. XVII. Terminal Reactive Oligooxyethylene Structures from Alkenes, Chlorine and O‐Nucleophiles and Their Transformation into Oxathiaalkanes The reaction of alkenes, chlorine and oxirane, dioxane, ethyleneglycole, oligoethylenglycoles, the monoethers of oligoethyleneglycoles, ethylene chlorohydrine or α‐hydro‐ω‐chloro‐oligooxyethylenes leads to compounds 6‐‐9, which contain mono or oligoether functions and one or two reactive terminal chlorine atoms. Oxathiaalkanes (10 and 12) were obtained in the reaction of such compounds with sodium mercaptides.