2022
DOI: 10.1038/s41428-022-00649-5
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Drag reduction by acrylate copolymers under thermohydrolysis

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Cited by 3 publications
(3 citation statements)
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“…Under aqueous conditions, the polymer chains stretch due to favorable solvent–polymer interaction, leading to the developing elastic retractive force in the polymer network that balances the reduction in the entropy associated with the resistance of the polymer to the swelling-induced polymer network. , The degree of macro or micro scale swelling is impacted by the PAM dissolution conditions, such as temperature, pH, and the coexistence of metallic ions. , In fact, the presence of mono and bimetallic ions allows the presence of incomplete swelling due to the electrostatic interactions between the exposed carboxylate groups with alkali and alkaline earth metal, forming aggregates, negatively impacting the polymeric linearity, and reducing their tendency for hydration. To overcome the salinity issue, polymeric structural modifications were usually performed by adding some surfactants or copolymers, such as PEO or XG, to the HPAM backbone to alter the net charge of the existing molecules. ,,, Recently, our research group has investigated the performance of virgin polymers of HPAM, XG, PEO, and mixtures of HPAM with XG and PEO at different salinity levels mimicking industrial conditions by using an industrial-scale fluid flow loop and a rotational rheometer. The effect of salinity levels on DR performance and degradation rates of virgin and mixture of polymers were studied and discussed.…”
Section: Factors Affecting Drag Reductionmentioning
confidence: 99%
“…Under aqueous conditions, the polymer chains stretch due to favorable solvent–polymer interaction, leading to the developing elastic retractive force in the polymer network that balances the reduction in the entropy associated with the resistance of the polymer to the swelling-induced polymer network. , The degree of macro or micro scale swelling is impacted by the PAM dissolution conditions, such as temperature, pH, and the coexistence of metallic ions. , In fact, the presence of mono and bimetallic ions allows the presence of incomplete swelling due to the electrostatic interactions between the exposed carboxylate groups with alkali and alkaline earth metal, forming aggregates, negatively impacting the polymeric linearity, and reducing their tendency for hydration. To overcome the salinity issue, polymeric structural modifications were usually performed by adding some surfactants or copolymers, such as PEO or XG, to the HPAM backbone to alter the net charge of the existing molecules. ,,, Recently, our research group has investigated the performance of virgin polymers of HPAM, XG, PEO, and mixtures of HPAM with XG and PEO at different salinity levels mimicking industrial conditions by using an industrial-scale fluid flow loop and a rotational rheometer. The effect of salinity levels on DR performance and degradation rates of virgin and mixture of polymers were studied and discussed.…”
Section: Factors Affecting Drag Reductionmentioning
confidence: 99%
“…Furthermore, the mechanism of DRPs and the level of drag reduction have been investigated extensively and attributed to the flowrate 26 , the concentration of DRPs 27 , temperature 28 , 29 , flow channel geometry 30 , 31 , flow orientation 32 , phase distribution 20 , 33 , viscoelasticity 34 , and DRP molecular weight and its bond structure 19 , 35 . According to Karami and Mowla 35 , two opinions explain the existing drag reduction mechanisms.…”
Section: Introductionmentioning
confidence: 99%
“…In fact, the linear polymeric chain structure is considered as a major role player in achieving an effective friction reducer structure. To avoid such challenging issues associated with working under saline conditions, several reported works suggested performing some polymeric structural modifications through introducing some surfactants or copolymers into the HPAM backbone to alter the net charge of the existing molecules. Generating such systems, through mixtures of polymer additives, will make up a tolerant friction reducer that is able to work under diverse saline conditions. , For instance, Mohammadtabar et al performed a comparative study on virgin polymers of HPAM, poly­(ethylene oxide) (PEO), and xanthan gum (XG) under turbulent flow conditions ( Re = 20 600) using a fluid flow loop.…”
Section: Introductionmentioning
confidence: 99%