Carbonized cloth (CC) of various types was modified with silicododecamolybdic acid (SiMo), poly o phenylenediamine (PPD) and stratified composite thereof. As a full value carbon material with highly developed surface, carbonized cloth with specific surface area about 15 m 2 /g shows good adsorption of SiMo from a solution as well as a serves a good electrode material for PPD electrosynthesis. If modified with SiMo/o phenylenediamine (OPD) composite, CC with specific surface area about 1500 m 2 /g accumu lates palladium ions from a solution.