“…The peaks at 30.9°, 35.5°, 47.1°, and 54.7° can be assigned to (204), (220), (306), and (330) faces of CoS 1.097 (JCPDS No.19‐0366), indicate that the CoS 1.097 sample is composed of β ‐CoS 1.097 phase with a hexagonal structure in the space group P63/mmc (194), while in the MnCo 2 S 4 ‐CoS 1.097 XRD spectrum, the extra peaks at 31.5°, 38.2°, and 50.4° are associated with the (311), (400), and (511) faces of MnCo 2 S 4 (JCPDS No.73‐1703), which is similar to the previous result. [ 38 ]…”