Double Mirozoki-Heck arylation of terminal alkenes using “ligand-free” pd catalytic systems

Abstract

The results of one-pot consecutive double arylation of terminal alkenes with aryl halides leading to three-substituted alkenes are presented. The advantages of the method when comparing with existing analogues are the combination of low reactive but available aryl bromides and aryl chlorides and «ligand-free» catalytic systems based on Pd(II) salt.