Double ionisation of disulfur

Abstract

Using time-of-flight multiple electron and ion coincidence techniques in combination with a helium gas discharge lamp and synchrotron radiation, the double ionisation spectrum of disulfur (S2) and the subsequent fragmentation dynamics of its dication are investigated. The S2 sample was produced by heating mercury sulfide (HgS), whose vapour at a suitably chosen temperature consists primarily of two constituents: S2 and atomic Hg. A multi-particle-coincidence technique is thus particularly useful for retrieving spectra of S2 from ionisation of the mixed vapour. The results obtained are compared with detailed calculations of the electronic structure and potential energy curves of S2+2 which are also presented. These computations are carried out using configuration interaction methodology. The experimental results are interpreted with and strongly supported by the computational results.