2012
DOI: 10.1080/15421406.2012.701120
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Doping Effect of Ethylcarbazole-Contained-Silole in Blue-Sensitive Organic Photoconductive Device

Abstract: The photoconductive characteristics of the solution-processed organic device was improved by doping 1, in poly(dioctylfluorenyl-co-benzo-thiadiazole) (F8BT). The maximum external quantum efficiency of 27% at −38 MV/m was achieved when the doping concentration of EtCz-silole was 40 wt%. This value was approximately 160 times higher than that of the reference device with F8BT only (0.17%). In addition, the signal-to-noise ratio (S/N), i.e., photocurrent density/dark current density was improved by doping EtCz-s… Show more

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Cited by 2 publications
(2 citation statements)
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“…[ 216 ] When F8BT ( N1 ) was blended with various electronaccepting materials, the blue-sensitive OPD performance was improved. [217][218][219][220][221][222] For example, a 40 wt% blend of 1,1-dimethyl-2,3,4,5-tetraphenylsilole (DMTPS, N5 ) in N1 improved the EQE to 7.6% under an electric fi eld of 2 × 10 5 V/cm in ∼250 nm-thick OPDs. [ 218 ] Importantly, the wavelength selectivity of the device was unaffected by the presence of the N5 due it absorbing exclusively in the near UV.…”
Section: Blue-sensitive Opdsmentioning
confidence: 99%
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“…[ 216 ] When F8BT ( N1 ) was blended with various electronaccepting materials, the blue-sensitive OPD performance was improved. [217][218][219][220][221][222] For example, a 40 wt% blend of 1,1-dimethyl-2,3,4,5-tetraphenylsilole (DMTPS, N5 ) in N1 improved the EQE to 7.6% under an electric fi eld of 2 × 10 5 V/cm in ∼250 nm-thick OPDs. [ 218 ] Importantly, the wavelength selectivity of the device was unaffected by the presence of the N5 due it absorbing exclusively in the near UV.…”
Section: Blue-sensitive Opdsmentioning
confidence: 99%
“…[217][218][219][220][221][222] For example, a 40 wt% blend of 1,1-dimethyl-2,3,4,5-tetraphenylsilole (DMTPS, N5 ) in N1 improved the EQE to 7.6% under an electric fi eld of 2 × 10 5 V/cm in ∼250 nm-thick OPDs. [ 218 ] Importantly, the wavelength selectivity of the device was unaffected by the presence of the N5 due it absorbing exclusively in the near UV. [ 217,223 ] The PFO derivative 'F8T2' ( N6 ) in blends with fullerene derivatives PC 61 BM ( B7 ) and the N -tosylated aziridino fullerene 'TsAF' ( N7 ) provided OPDs with FWHMs of ≈100 nm (λ max = 460 nm) [ 183,224 ] although a tail from the fullerene derivatives was evident, particularly for the N6 : B7 (1:4) OPD device.…”
Section: Blue-sensitive Opdsmentioning
confidence: 99%