We have studied the electronic structure of Ba(Fe 1−x Mn x ) 2 As 2 (x=0.08), which fails to become a superconductor in spite of the formal hole doping like Ba 1−x K x Fe 2 As 2 , by photoemission spectroscopy and X-ray absorption spectroscopy (XAS). With decreasing temperature, a transition from the paramagnetic phase to the antiferromagnetic phase was clearly observed by angle-resolved photoemission spectroscopy. XAS results indicated that the substituted Mn atoms form a strongly hybridized ground state. Resonance-photoemission spectra at the Mn L 3 edge revealed that the Mn 3d partial density of states is distributed over a wide energy range of 2-13 eV below the Fermi level (E F ), with little contribution around E F . This indicates that the dopant Mn 3d states are localized in spite of the strong Mn 3d-As 4p hybridization and split into the occupied and unoccupied parts due to the on-site Coulomb and exchange interaction. The absence of superconductivity in Ba(Fe 1−x Mn x ) 2 As 2 can thus be ascribed both to the absence of carrier doping in the FeAs plane, and to the strong stabilizaiton of the antiferromagnetic order by the Mn impurities. PACS numbers: 74.25.Jb,74.70.Xa,71.18.+y, Since the discovery of high-T c superconductivity in the iron pnictides 1 , various types of carrier doping have been successfully performed to induce superconductivity. Superconductivity appears in BaFe 2 As 2 (Ba122) by hole doping realized by K substitution for the Ba sites 2 or by electron doping realized by Co 3 , Ni, or Cu substitution 4 for the Fe sites. However, Mn substitution for the Fe sites does not induce superconductivity and antiferromagnetic order persists in Ba(Fe 1−x Mn x ) 2 As 2 (Mn-Ba122) in the entire doping range x below ∼ 60 K 5,6 . The orthorhombic distortion of Ba122 disappears at x ∼ 0.09 and the system enters a tetragonal phase. As shown in Fig. 1, the resistivity of Mn-Ba122 5 shows a jump at the magneto-structural phase transition temperature and gradually increases below it. This behavior is contrasted with the metallic behaviors of the parent compound and the hole-doped Ba 1−x K x Fe 2 As 2 (K-Ba122) 7 , where the resistivity drops below the transition temperature. A neutron scattering experiment on Mn-Ba122 8 has revealed competition between the stripe-type spin-density-wave (SDW) order [Q Q Q stripe =( 1 2 , 1 2 , 1)] seen in the parent compound and a G-type antiferromagnetic order [Q Q Q G-type =(1, 0, 1)] predominant in the tetragonal phase; in the orthorhombic phase, there are additional inelastic spin excitation peaks which represent the Gtype antiferromagnetic fluctuations. This result indicates that Mn doping predominantly introduces an additional local magnetic order which is distinct from the magnetic order of the parent compound, instead of suppressing the long-range SDW order of the parent compound. It is theoretically suggested that G-type magnetic fluctuations strongly suppress the s ± superconducting state 9 . According to the proximity scenario of iron-based superconductors to Mott ...