“…41 Noticeably, the intensities of CuTPP-Cy and NiTPP-Cy are higher, compared with those of H 2 TPP-Cy, which may be caused by increased crystallinity with the introduction of metal. 42 To further illustrate the connection between s -heptazine and porphyrins units in MTPP-Cys, FT-IR measurements were performed. As presented in Fig.…”
Three novel porphyrin-heptazine-based conjugated organic polymers (MTPP-Cys, M = H2, Ni, Cu) have been constructed, and an intramolecular donor-acceptor (D-A) structure has been formed by the electron-rich porphyrin and electron-deficient...
“…41 Noticeably, the intensities of CuTPP-Cy and NiTPP-Cy are higher, compared with those of H 2 TPP-Cy, which may be caused by increased crystallinity with the introduction of metal. 42 To further illustrate the connection between s -heptazine and porphyrins units in MTPP-Cys, FT-IR measurements were performed. As presented in Fig.…”
Three novel porphyrin-heptazine-based conjugated organic polymers (MTPP-Cys, M = H2, Ni, Cu) have been constructed, and an intramolecular donor-acceptor (D-A) structure has been formed by the electron-rich porphyrin and electron-deficient...
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