2020
DOI: 10.1002/cphc.201901115
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Does Pressure Break Mirror‐Image Symmetry? A Perspective and New Insights

Abstract: This paper is aimed at dissecting and discussing the effect of high pressure on chirogenesis, thus unveiling the role of this universal force in astrochemical and primeval Darwinian scenarios. The first part of this contribution revisits the current status and recent experiments, most dealing with crystalline racemates, for which generation of metastable conglomeratic phases would eventually afford spontaneous resolution and hence enantioenriched mixtures. We then provide an in-depth thermodynamic analysis, ba… Show more

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