Dodecahedrane minibead polymers

Bánfalvi, Gáspár

doi:10.1039/c3ra43628d

Cited by 5 publications

(2 citation statements)

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“…The lon networks were constructed from 12 equiv nodes comprising six centroids of the adamantane cores (Cg1) and six Ag(I) nodes arranged in alternation (Figure ). The resultant building blocks possessed three six-membered fused rings in boat conformations and two six-membered rings in chair conformations. CP puckering analyses showed ideal chair and boat conformations for 1a – d , indicating genuine lon networks (Supporting Information section S5).…”

Section: Resultsmentioning

confidence: 99%

“…The dia networks were constructed from 10 equiv nodes comprising four Cg1 and six Ag(I) nodes (or vice versa) arranged in alternation (Figure 2). 32 The resultant building block possessed four six-membered fused rings in chair conformations. CP puckering analysis for the chairs in 2a−c indicated genuine dia networks (Figure 1; Supporting Information section S5).…”

Section: ■ Resultsmentioning

confidence: 99%

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Synthesis of Diamondoid and Lonsdaleite Networks from the Same Ag(I)–Ligand Combination, with Lonsdaleite the Softer Network

Patil

Dickinson

Tremlett

et al. 2016

Crystal Growth & Design

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The design and synthesis of a Lonsdaleite (lon) network is an attractive and challenging supramolecular target. Our reticular synthesis strategy of slow diffusion of solutions of a simple rigid tetrahedral ligand and a Ag(I) metal ion, at room temperature and atmospheric pressure, resulted in both lon-MOFs and diamondoid (dia-MOFs) and associated 2D honeycomb networks. Solvent appeared to play a key role in templating the formation of these related networks. Nanoindentation studies show that a dia-MOF was 42% harder than a lon-MOF counterpart. The lon-MOFs were thermally stable and retained integrity until 370 °C while dia-MOFs exhibited stepwise collapse after initial loss of solvents. As lon networks are often only qualitatively identified, Cremer−Pople ring puckering analysis was used to quantify the degree of distortion in the lon and related 4-connected 6 6 networks.

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Section: Resultsmentioning

confidence: 99%

Section: ■ Resultsmentioning

confidence: 99%