This work represents development of the first phase field models and detailed study solidsolid transformations via intermediate melting within nanometer size interface. Such phase transformations can occur in different materials, including HMX energetic crystals, PbTiO 3 nanowires, complex pharmaceutical substances, electronic and geological materials, as well as colloidal, and superhard materials. A thermodynamically consistent phase field model for three phases is developed using two polar order parameters. It includes the effect of energy and width of solid-solid and solid-melt interfaces, interaction between two solid-melt interfaces, temperature, mechanics, and interface stresses. The derived thermodynamic potential satisfies