“…[1][2][3][4][5][6] While the hydrogenation of CO 2 can afford av ariety of products and is ad esirable process in terms of atom economy,t he use of silane reductantsa llows for the use of significantly milder reaction conditions (T < 100 8C, P CO2 < 3atm), and benefits thermodynamically from the stability of the generated products featuring SiÀOb onds. [7][8][9] In addition, the use of silanesh as allowed for the development of catalytic systemsw hich exercise greaterc ontrolo ver selectivity for products with different carbon oxidationl evels,i ncluding silyl formates,s ilyl acetals, methoxysilanes and methane (which is formed in conjunction with bis(silyl)ethers). [8][9][10][11][12][13] Thus, av arietyo fh omogenousc atalytic systemsb ased on metals (Pd/Pt, [14][15][16][17] Rh, [18] Re, [19,20] Ru, [21][22][23][24][25][26] Ir, [8,[27][28][29][30] Co, [13,31] Mn, [12] Zr, [32,33] Cu, [34][35][36][37][38] Ni, [39]…”