Divergent Synthesis and Semiconductor Properties of Dithienobenzothiazoles with S•••N and S•••S Interactions Controlling Molecular Arrangement in Crystal
Abstract:Seven dithienobenzothiazole (DBT) derivatives 1a–g were synthesized by one-step functionalization of a common precursor and investigated for their semiconducting properties. The DBT core possesses a three-directional annulated -conjugated plane which enables variable intermolecular interaction, such as S•••S and S•••N interactions. X-ray single-crystal structural analyses confirmed that the molecular arrangements of 1b (the diethyl and ethylthienyl derivative) and 1c (the di(n-propyl) and n-propylthienyl deri… Show more
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