Abstract:Auto-oxidation of aliphatic aldehydes generates alkyl radicals and alkanoyl radicals, which can be intercepted to generate carbon-carbon bonds. However, the highly reactive and unstable radical intermediates make the controlling selectivity alkylation and alkanoacylation especially challenging. Herein, we report a sustainable and controllable protocol for the auto-oxidative alkylation and alkanoacylation of quinoxalin-2(1H)-ones with good reactivity and selectivity. This protocol was presented in a green and s… Show more
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