Dithienylethene-Based Photoswitchable Phosphines for the Palladium-Catalyzed Stille Coupling Reaction
Anastasiia Sherstiuk,
Agustí Lledós,
Peter Lönnecke
et al.
Abstract:Homogeneous transition metal catalysis is a constantly
developing
field in chemical sciences. A growing interest in this area is photoswitchable
catalysis, which pursues in situ modulation of catalyst
activity through noninvasive light irradiation. Phosphorus ligands
are excellent targets to accomplish this goal by introducing photoswitchable
moieties; however, only a limited number of examples have been reported
so far. In this work, we have developed a series of palladium complexes
capable of catalyzing the … Show more
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