Dithieno[3,2-b:2′,3′-d]phospholes: A Look Back at the First Decade

Romero‐Nieto, Carlos; Baumgartner, Thomas

doi:10.1055/s-0032-1317804

Cited by 73 publications

(83 citation statements)

References 6 publications

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“…Them ore robust fused dithienophosphole oxides [169] and dibenzophosphole oxides have been embedded into various conjugated polymers and explored in organic electronic applications. [170] Fori nstance,h igh performance OSCs using phosphole oxide polymer 98 (Figure 27 c) in combination with PC 71 BM gave PCEs of up to 6.10 %(X= S) and 7.08 %(X= Se).…”

Section: Reviewsmentioning

confidence: 99%

Functional Polymeric Materials Based on Main‐Group Elements

2019

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The past decade has witnessed tremendous advances in the synthesis of polymers that contain elements from the main groups beyond those found in typical organic polymers. Unique properties that arise from dramatic differences in bonding and molecular geometry, electronic structure, and chemical reactivity, are exploited in diverse application fields. Herein we highlight recent advances in inorganic backbone polymers, discuss how Lewis acid/base functionalization of polymers results in unprecedented reactivity, and survey conjugated hybrids with unique electronic structures for sensor and device applications.

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Section: Reviewsmentioning

confidence: 99%

Functional Polymeric Materials Based on Main‐Group Elements

2019

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“…However, the supramolecular chemistry and self‐organization of these compounds are rarely reported in the literature. In the context of our work with the dithienophosphole building block (Figure b), we have discovered the unique and desirable photophysical and electronic properties of this compound . However, to integrate the building block into functional devices, we determined that its supramolecular and self‐organization properties needed to be developed through the rational design of the target molecule.…”

Section: Phosphole Lipidsmentioning

confidence: 99%

Organophosphorus Avenues toward Self‐Assembled Conjugated Soft Materials

Wang

Baumgartner

2014

The Chemical Record

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Self-assembly is nature's most powerful tool for constructing the physical world. Self-assembly has also become an important theme in organic materials research. Within our research program on π-conjugated organophosphorus materials, we have recently aimed to combine the unique optoelectronic properties of organophosphorus building blocks with self-assembly features. Our novel organophosphorus-based chromophore mesogens self-assemble into complex structures, such as liquid crystals and organogels. More importantly, intriguing optoelectronic properties not present in the original building blocks are also produced as a result. These results have opened up a rich chemistry toward smart functional materials that is currently being further exploited in our group.

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“…Die robusteren kondensierten Dithienophospholoxide [169] und Dibenzophospholoxide wurden in verschiedene konjugierte Polymere eingebaut und in organisch-elektronischen Anwendungen getestet. [170] Zum Beispiel ergaben leistungsstarke OSCs mit Phospholoxid-Polymer 98 (Abbildung 27 c) in Kombination mit PC 71 BM PCE-Werte bis zu 6.10 (X = S) und 7.08 %( X = Se).…”

Section: Angewandte Chemieunclassified

Funktionelle polymere Materialien auf der Basis von Hauptgruppen‐Elementen

Vidal

Jäkle

2019

Angewandte Chemie

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In den letzten zehn Jahren wurden enorme Fortschritte bei der Synthese von Polymeren erzielt, die Hauptgruppen‐Elemente enthalten und über die typischen organischen Polymere hinausgehen. Einzigartige Eigenschaften, die sich aus drastischen Unterschieden in Bindung und molekularer Geometrie, elektronischer Struktur und chemischer Reaktivität ergeben, werden in den unterschiedlichsten Anwendungsbereichen genutzt. In dem Aufsatz werden die jüngsten Fortschritte bei Polymeren mit anorganischem Rückgrat hervorgehoben, es wird diskutiert, wie die Lewis‐Säure/Base‐Funktionalisierung von Polymeren zu beispielloser Reaktivität führt, und es werden konjugierte Hybride mit spezifischen elektronischen Strukturen für die Sensorik sowie Anwendungen in Organische‐Elektronik‐Geräten vorgestellt.

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Dithieno[3,2-b:2′,3′-d]phospholes: A Look Back at the First Decade

Cited by 73 publications

References 6 publications

Functional Polymeric Materials Based on Main‐Group Elements

Functional Polymeric Materials Based on Main‐Group Elements

Organophosphorus Avenues toward Self‐Assembled Conjugated Soft Materials

Funktionelle polymere Materialien auf der Basis von Hauptgruppen‐Elementen

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