“…A second, and related, goal is to be able to predict the spreading of solute plumes, both in the direction of flow and transverse to it (Berkowitz & Scher, ; Gelhar et al, ; Neuman, ; Sahimi et al, ; Sahimi, Davis, et al, ; Sahimi, Heiba, et al, ; Sahimi, Hughes, et al, ; Sahimi & Imdakm, ). This problem will be taken up later in this review, where we describe how the percolation concepts used to predict the hydraulic conductivity distribution (Hunt, ; Hunt et al, ) can also be used to predict the longitudinal dispersion coefficient, the arrival time distribution of solute, the dispersivity, and the scaling of chemical reaction rate (Hunt, Skinner, et al, ; Hunt, , ). Although quantitative prediction requires a particular model, for many purposes, including dispersion and the scaling of chemical reaction rates, the details of the porous medium are less important than the parameters provided by percolation theory that are related most directly to the connectivity of the fluid flow paths through the medium (Lee et al, ; Sahimi et al, ; Sheppard et al, ).…”