Printed circuit board (PCB), as the basic mechanically supports of electronic devices, is widely used in circuit, radio frequency (RF), and other fields. [1,2] Copper is the most commonly used conductive material in the PCB structure due to its high electrical conductivity and matured manufacture techniques. [3] Despite the advantages, with the increasing demand of electronic products, metal waste is becoming a severe problem, as it can cause significant environment pollutions. [4-6] Metal materials also suffer from high prices (because of their limited reserves), relatively poor flexibility, large density, and easily oxidized. As communication technologies developing, copper and other traditional metals-based PCB are becoming difficult to meet the new requirements for 5G communication devices, such as of being lightweight, flexible, miniaturized, and chemically stable under certain severe conditions. [7] Therefore, it is necessary to find a suitable material to realize metal substitution in the field of electronic products based on PCB. Many attempts have been made to find the right candidates for such substitution of copper so far. Recently, carbon-based allotropic materials, such as carbon nanotubes (CNTs), carbon fibers, graphene, and fullerenes, have been widely investigated in the fields of antennas, [8-10] sensors, [11,12] transistors, [13] and other electronic fields, [14,15] given that they are abundant in nature and their advanced properties of lightweight, corrosion resistant, and environmental friendly. For instance, CNTs not only have excellent mechanical properties, biocompatibility, and chemical stability, [16-18] but also have the disadvantages of low conductivity, complex film-forming process, and high contact resistance. [19-21] Fullerenes, such as the CNTs, also suffer from low conductivity and difficult film forming, [22] which lead to the problems of high loss and unsatisfactory performance