Silica films with Ln3+-doped LaF3 nanoparticles were prepared by sol gel method and their luminescent
properties were studied as a function of the temperature. Significant improvements in the luminescent
properties, in terms of the lifetime for the 4I13/2 level of Er3+ (∼10.9 ms), 4F3/2 level of Nd3+ (∼171 μs),
and 5F3 level of Ho3+ (∼6 μs), were obtained when corresponding nanoparticles are incorporated in
silica films rather than the bare ions. In addition to the LaF3 as the low phonon energy matrix, the absence
of lanthanide ion clustering, and the increased distance between the OH groups of the silica matrix and
the lanthanide ions, are responsible for the observed improvements in the luminescent properties for
nanoparticle incorporated silica films. Lifetime values could be further improved by incorporating core−shell nanoparticles (the doped LaF3 core surrounded by an undoped shell of LaF3) in the silica matrix,
as a result of further reduction of the nonradiative pathways.