Distinct Properties of Nanofibrous Amorphous Ice

Cai, Fanyi; Xu, Chunye; Zheng, Jianming

doi:10.3390/ma7127653

Materials

2014

DOI: 10.3390/ma7127653

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Distinct Properties of Nanofibrous Amorphous Ice

Fanyi Cai

Chunye Xu

Jianming Zheng

Abstract: We make glassy water in the form of nanofibers by electrospraying liquid water into a hyperquenching chamber. It is measured with means of differential scanning calorimetry, wide angle X-ray diffraction and Raman spectroscopy. It is found that two apparent glass transitions at Tg1 = 136 K and Tg2 = 228 K are detected and non-crystallized water is observed at temperatures up to 228 K. This finding may expand the research objects for liquid water at low temperatures.

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Low-Dimensional and Confined Ice

Cui

et al. 2023

Annu. Rev. Mater. Res.

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Owing to its unique structure, morphology, and crystal quality, low-dimensional (L-D) ice has attracted increasing attention in recent years. With a size (at least in one dimension) between that of a single water molecule and a snowflake, L-D ice does not only appear as an intermediate state during the dimensional change but can also manifest extraordinary characteristics, from its molecular structures to its physical properties, which offer exciting opportunities for a better understanding and utilization of ice. In this article, we start with a brief introduction to the crystal growth, structure, and typical characterization techniques of ice and then review recent progress in the study of crystal growth, molecular structures, phase morphologies, and physical properties of zero-, one-, and two-dimensional (0-, 1-, and 2D) ice. Extraordinary behaviors of ice in low dimensions and extreme conditions are highlighted. Finally, the future outlook for the physical study and technological applications of L-D ice is briefly discussed. Expected final online publication date for the Annual Review of Materials Research, Volume 53 is July 2023. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.

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Low-Dimensional and Confined Ice

Cui

et al. 2023

Annu. Rev. Mater. Res.

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Distinct Properties of Nanofibrous Amorphous Ice

Cited by 1 publication

References 34 publications

Low-Dimensional and Confined Ice

Low-Dimensional and Confined Ice

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