Distinct photomechanical responses of two new 1,3-dimethylbarbituric acid derivative crystals

Nag, Sayak; Emmerling, Franziska; Tothadi, Srinu; Bhattacharya, Biswajit; Ghosh, Soumyajit

doi:10.1039/d4ce00233d

CrystEngComm

2024

DOI: 10.1039/d4ce00233d

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Distinct photomechanical responses of two new 1,3-dimethylbarbituric acid derivative crystals

Sayak Nag,

Franziska Emmerling,

Srinu Tothadi

et al.

Abstract: Molecular crystals that exhibit photomechanical responses hold great promise as photoactuators and other smart materials in various fields. Here, we synthesized two new barbituric acid derivative crystals (crystals 1 and...

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Advancing Light‐Driven Elastic Crystals: Toward Sustainable Applications in Robotic Arms, Information Identification, and Optical Waveguides

Peng,

Yang,

Zhao

et al. 2024

Advanced Optical Materials

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An innovative elastic crystal based on barbituric acid derivatives (HBDT), which uniquely alters its fluorescence intensity under light exposure is developed. This crystal exhibits significant bending under 365 nm, 450 nm, white light, and sunlight while retaining its elasticity post‐bending. The photomechanical effect of this crystal is driven by intermolecular [2+2] cycloaddition reactions, resulting in light‐activated fluorescence enhancement. These properties open new avenues for applications in robotic arms, information identification, and optical waveguides, presenting a groundbreaking approach for sustainable and flexible crystal applications in material science and optical technology.

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Advancing Light‐Driven Elastic Crystals: Toward Sustainable Applications in Robotic Arms, Information Identification, and Optical Waveguides

Peng,

Yang,

Zhao

et al. 2024

Advanced Optical Materials

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show abstract

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Distinct photomechanical responses of two new 1,3-dimethylbarbituric acid derivative crystals

Abstract: Molecular crystals that exhibit photomechanical responses hold great promise as photoactuators and other smart materials in various fields. Here, we synthesized two new barbituric acid derivative crystals (crystals 1 and...

Cited by 1 publication

References 54 publications

Advancing Light‐Driven Elastic Crystals: Toward Sustainable Applications in Robotic Arms, Information Identification, and Optical Waveguides

Advancing Light‐Driven Elastic Crystals: Toward Sustainable Applications in Robotic Arms, Information Identification, and Optical Waveguides

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