Distinct Intercalation and Conduction Behaviors within an Isostructural Series Ba5R2Al2SnO13
Alex J. Brown,
Oliver J. Wagstaff,
Ivana Radosavljevic Evans
et al.
Abstract:The series Ba 5 R 2 Al 2 SnO 13 (R = In, Y, Er, Ho, Tb) has been synthesized and structurally characterized by X-ray and neutron powder diffraction. All members have oxygen-deficient 10-layer hexagonal (10H) perovskite-type structures at high temperature and gain mass on cooling equivalent to ∼0.5 oxygen atoms per formula unit, observed by both thermogravimetric analysis and the occupancy of a vacant site in the oxygen substructure refined against neutron powder diffraction data. The origin of this mass gain v… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.