This study aims to explain the dielectric relaxation in sodium silicate (Na2SiO3) and its direct dependence on temperature across various frequencies. The study examines and elucidates the involvement of various types of polarization in the thermo-active dielectric relaxation process. Both low-frequency dielectric dispersion and complex impedance play pivotal roles in controlling the thermo-active dielectric relaxation process. Utilizing complex data plots, the study actively, and prominently illustrates the relaxation process.