“…Various approaches to generate dissymmetric particles have been reported in the recent literature. These Janus-type particles have been obtained either by protection/deprotection mechanisms, focused laser-induced reactions, cojetting of parallel polymer solutions under the influence of an electrical field, anisotropic electroless deposition, or with microfluidic techniques . However, so far most of the methods used to generate such objects need to break the symmetry by introducing interfaces like in the case of sputtering, , stamp coating, , and Langmuir−Blodgett-based techniques .…”