We introduce the discording power of a unitary transformation, which assesses its capability to produce quantum discord, and analyze in detail the generation of discord by relevant classes of two-qubit gates. Our measure is based on the Cartan decomposition of two-qubit unitaries and on evaluating the maximum discord achievable by a unitary upon acting on classical-classical states at fixed purity. We found that there exist gates which are perfect discorders for any value of purity, and that they belong to a class of operators that includes the √ SWAP. Other gates, even those universal for quantum computation, do not posses the same property: the CNOT, for example, is a perfect discorder only for states with low or unit purity, but not for intermediate values. The discording power of a two-qubit unitary also provides a generalization of the corresponding measure defined for entanglement to any value of the purity. The primary aim of the science of quantum information is the exploitation of the quantum structure of nature for information processing and communication tasks. Among the quantum features of a physical system, entanglement is usually considered the prominent resource, providing speed-up in various quantum information and communication tasks [1]. In the realm of mixed-state quantum-information, however, instances are known where quantum advantages are obtained in the presence of little or no entanglement. In fact, quantum discord [2,3] has been proposed as the source behind this enhancement [4], and some indications in this direction have been given [5][6][7][8]. The notion of nonclassicality springing from information theory has been also discussed in comparison with that coming from phase-space constraints [9].Although introduced in the context of environment induced decoherence, quantum discord has been then related to the performance of quantum and classical Maxwell's demons [10] and to the thermodynamic efficiency of a photo-Carnot engine [11], as well as the total entanglement consumption [12], and the minimum possible increase of quantum communication cost [13] in state merging protocols. Furthermore, its propagation properties have been studied in [14] in connection with micro-causality and in [15] for quantum spin channels.Quantum discord can be activated into distillable entanglement [16,17], and has been shown to be a resource in quantum state discrimination [18] and quantum locking [19]. It has been also shown [20,21] that discord quantifies the minimum damage made by a decoherence process to the performance of many quantum information processing protocols, including teleportation, distillation and dense coding.In continuous variable systems, Gaussian quantum discord [22,23] has been experimentally measured [24][25][26] and represents a measure of the advantage provided by coherent quantum systems over their classical counterpart. It has been also suggested [27] that the geometric quantum discord [28] is the optimal resource for remote quantum state preparation, though the interpretation of ...