Dissociation dynamics of excited neutral fragments of gaseousSiCl4following Si2pand Cl2p

State-selective enhanced production of positive ions and excited neutral fragments of gaseous CH2Cl2following ClLu1, Chen2, Lee3 et al. 2010Phys. Rev. ASelf Cite

“…Extensive work seeking to understand the causes of the mechanism of dissociation of these excited neutral species is indispensable to obtain a comprehension of the chemical dynamics. Neutral fragments have been detected from molecules adsorbed on surfaces via core-level excitation [6,[15][16][17][18]. Pathways existing for neutral fragmentation have been little investigated partly because of challenges in thorough probing of gaseous molecules, but, if the neutral fragments are in an excited state, uv-visible * Corresponding author: ktlu@nsrrc.org.tw dispersed fluorescence spectra prove to be a powerful tool for the investigation of neutral fragmentation of molecules with excitation.…”

“…Pathways existing for neutral fragmentation have been little investigated partly because of challenges in thorough probing of gaseous molecules, but, if the neutral fragments are in an excited state, uv-visible * Corresponding author: ktlu@nsrrc.org.tw dispersed fluorescence spectra prove to be a powerful tool for the investigation of neutral fragmentation of molecules with excitation. Measurement of the uv-visible fluorescence yield as a function of photon energy can provide valuable information about the deexcitation and fragmentation of core-excited molecules through a capability to detect both neutral and ionic fragments [6,16,18], but few reports have appeared of coordinated investigations of ionic and excited neutral fragments produced by core-level excitation of gaseous molecules.…”