We investigate the surface electronic structures of polar 1T'-MoTe2, the Weyl semimetal candidate realized through the nonpolar-polar structural phase transition, by utilizing the laser angle-resolved photoemission spectroscopy combined with first-principles calculations. Two kinds of domains with different surface band dispersions are observed from a single-crystalline sample. The spin-resolved measurements further reveal that the spin polarizations of the surface and the bulk-derived states show the different domain-dependences, indicating the opposite bulk polarity. For both domains, some segment-like band features resembling the Fermi arcs are clearly observed. The patterns of the arcs present the marked contrast between the two domains, respectively agreeing well with the slab calculation of (0 0 1) and (0 0 -1) surfaces. The present result strongly suggests that the Fermi arc connects the identical pair of Weyl nodes on one side of the polar crystal surface, whereas it connects between the different pairs of Weyl nodes on the other side. Weyl nodes) at the Fermi level (EF). The bulk electronic structure of Weyl semimetals is characterized by the spin-polarized Weyl cone dispersions formed through the breaking of either time-reversal or space-inversion symmetry [1][2][3][4]. At the surface, on the other hand, the chiral charge associated with the Weyl nodes warrants the existence of the gapless surface states, socalled Fermi arcs that connect the two-dimensionally (2D) projected Weyl nodes. Due to these unusual bulk and surface electronic states, a variety of new magnetoelectric phenomena have been predicted [4][5][6][7][8][9]. Until now, several experimental verifications of realistic Weyl semimetal compounds have been raised (eg. the TaAs family [10][11][12] The single-crystalline 1T'-MoTe2 was synthesized as reported elsewhere [19,20].ARPES at 25 K was performed using the He-discharge lamp (21.2 eV) and the fourth harmonic generation of Ti:sapphire laser (6.43 eV, s-polarized light) [28], with a VG-Scienta R4000WALanalyzer. The total energy resolution was set to 10 and 3 meV, respectively. For the laser-SARPES at 25 K and the ARPES at 100 K, a 6.99 eV laser (s-polarized light) and a ScientaOmicron DA30Lanalyzer mounted with two sets of very-low-energy electron diffraction spin detectors were used at the Institute of Solid State Physics (ISSP), The University of Tokyo [29]. The total energy resolution was set to 30 and 3 meV, respectively. Samples were cleaved in situ at room temperature. All measurements were performed in ultrahigh vacuum better than 1×10 -10 Torr.Electronic structure calculations were performed within the context of density functional theory (DFT) using the Perdew-Burke-Ernzerhof exchange-correlation functional as implemented in the VASP program [30,31]. Relativistic effects were fully included. The structure parameters in Ref.[14] were used, and the corresponding Brillouin zone was sampled by a 20 × 10 × 5 k-mesh. To focus on the near-EF electronic structure, the ARPES images...