Abstract:Traditional Li-ion battery electrodes are highly crystalline materials in which the ions are intercalated between atomic layers or channels in the atomic lattice. Such electrodes are typically characterized by retaining their crystallinity for many charge-discharge cycles. However, a number of electrode materials undergo an irreversible loss of crystallinity upon Li-intercalation. Examples of such materials are rutile TiO2 and orthorhombic V2O5, which loses long range order upon intercalation of >0.8 and >2 Li… Show more
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