We study topological phases of time-reversal invariant singlet superconductors in three spatial dimensions. In these particle-hole symmetric systems the topological phases are characterized by an even-numbered winding number ν. At a two-dimensional (2D) surface the topological properties of this quantum state manifest themselves through the presence of ν flavors of gapless Dirac fermion surface states, which are robust against localization from random impurities. We construct a tightbinding model on the diamond lattice that realizes a topologically nontrivial phase, in which the winding number takes the value ν = ±2. Disorder corresponds to a (non-localizing) random SU(2) gauge potential for the surface Dirac fermions, leading to a power-law density of states ρ(ǫ) ∼ ǫ 1/7 . The bulk effective field theory is proposed to be the (3+1) dimensional SU(2) Yang-Mills theory with a theta-term at θ = π.PACS numbers: 73.20.At, 74.25.Fy, 73.20.Fz, 03.65.Vf Bloch-Wilson band insulators are commonly believed to be simple and well understood electronic states of matter. However, recent theoretical [1,2,3,4,5,6] and experimental [7,8] progress has shown that band insulators can exhibit unusual and conducting boundary modes, which are topologically protected, analogous to the edge states of the integer quantum Hall effect (QHE). These so-called Z 2 topological insulators (also known as 'quantum spin Hall' insulators), which exist in two-and threedimensional (3D) time-reversal invariant (TRI) systems, are characterized by a topological invariant, similar to the Chern number of the integer QHE. Given these newly discovered topological states, one might wonder whether there exists a general organizing principle for topological insulators. Indeed, the integer QHE and the Z 2 topological insulators are in fact part of a larger scheme, discussed in Ref. [6], which provides an exhaustive classification of topological insulators and superconductors in terms of spatial dimension and the presence or absence of the two most generic symmetries of the Hamiltonian, time-reversal and particle-hole symmetry [9].Using this classification scheme which was originally introduced in the context of disordered systems [10], it was shown in Ref.[6] that, besides the 3D Z 2 topological insulator, there are precisely four more 3D topological quantum states. Among these there is one which is particularly interesting from the point of view of possible experimental realizations. It is called the topological superconductor in symmetry class CI in the terminology of Ref.[6] and can be realized in time-reversal invariant singlet BCS superconductors. While the bulk is fully gapped in this topological quantum state, there are gapless robust Dirac states at the two-dimensional boundary. The CI topological superconductor is unique among 3D topological quantum states in that it does not break SU(2) spin rotation symmetry, and therefore supports the transport of spin through gapless surface modes. The different topological phases of the CI topological supercon...