Plasma has been proposed as an alternative strategy to
treat organic
contaminants in brines. Chemical degradation in these systems is expected
to be partially driven by halogen oxidants, which have been detected
in halide-containing solutions exposed to plasma. In this study, we
characterized specific mechanisms involving the formation and reactions
of halogen oxidants during plasma treatment. We first demonstrated
that addition of halides accelerated the degradation of a probe compound
known to react quickly with halogen oxidants (i.e., para-hydroxybenzoate) but did not affect the degradation of a less reactive
probe compound (i.e., benzoate). This effect was attributed to the
degradation of para-hydroxybenzoate by hypohalous
acids, which were produced via a mechanism involving halogen radicals
as intermediates. We applied this mechanistic insight to investigate
the impact of constituents in brines on reactions driven by halogen
oxidants during plasma treatment. Bromide, which is expected to occur
alongside chloride in brines, was required to enable halogen oxidant
formation, consistent with the generation of halogen radicals from
the oxidation of halides by hydroxyl radical. Other constituents typically
present in brines (i.e., carbonates, organic matter) slowed the degradation
of organic compounds, consistent with their ability to scavenge species
involved during plasma treatment.