A micro-arc oxidation coating on Ti6Al4V alloy was modified by addition of micro-Al 2 O 3 particles to a sodium phosphate solution. The coating structure and phase were characterized by scanning electron microscopy and X-ray diffraction, and the oxidation resistance and thermal shock properties of the coating were investigated. Results showed that a coating denser than the original coating was produced. This new coating was composed of Al 2 TiO 5 and TiO 2 . The oxidation resistance and thermal shock property of the coating improved with addition of Al 2 O 3 particles to the electrolyte relative to the sample prepared without the particles in the electrolyte. Moving Al 2 O 3 particles were adsorbed on the coating surface and penetrated through it. As a result, the phase structure and properties of the original coating were modified.