The estimation of mercury (Hg) emission fluxes from geothermal sources has a large uncertainty due to the paucity of relevant measurements. Using a high-precision, easy-to-deploy, and cost-effective passive air sampling method, we assessed the spatial concentration variability of gaseous elemental Hg (GEM) at three locations at or near geothermal sources in the Taupo Volcanic Zone on the North Island of New Zealand: Karapiti, Ngapouri, and Whakaari/White Island. GEM concentrations, averaged over periods of 1−4 months, were elevated above Southern Hemisphere background levels at all locations. Fumaroles were identified as major point sources of Hg, with levels in their vicinity exceeding background by up to 2 orders of magnitude (4.0−110 ng m −3 ). From a spatial GEM concentration map at Karapiti, we estimate an area-normalized Hg emission flux of ∼60 μg m −2 d −1 . Contamination of samplers during storage was identified and corrected using field blanks. While this rendered the results for background samples semiquantitative, the main conclusions regarding spatial concentration variability and emission strength were unaffected. Isotopic analysis showed that the isotopic signatures of samples collected in the vicinity of fumaroles had negative mass-dependent fractionation (MDF, δ 202 Hg) and near-zero odd mass-independent fractionation (MIF, Δ 199 Hg) values compared to samples collected at a distance from geothermal sources, which had positive MDF and negative odd MIF values. With the ability for high spatial resolution measurement and reliable isotopic characterization of GEM, the passive air sampler is a useful tool to characterize Hg emissions from geothermal sources.