“…Geochemical monitoring of soil gases has been widely used as a powerful tool for geothermal exploration (Badalamenti et al, 1984(Badalamenti et al, , 1988Bertami et al, 1990;Finlayson, 1992;Chiodini et al, 1998), exploiting oil and gas reserves (Gregory and Durrance, 1985;McCarthy and Reimer, 1986), and other applications such as earthquake prediction (Irwin and Barnes, 1980;King, 1980;Wakita et al, 1980;Sugisaki et al, 1983;Oskarsson, 1984;Satake et al, 1984;Sato et al, 1984;Wakita, 1996;Salazar et al, 2002;Kameda et al, 2003;Giammanco et al, 2006) and volcano surveillance (Sato and McGee, 1982;Badalamenti et al, 1991;Baubron et al, 1991;Barberi and Carapezza, 1994;Valenza, 1994;Giammanco et al, 1995aGiammanco et al, , 1995bGiammanco et al, 1996;Granieri et al, 2009;Federico et al, 2011;Camarda et al, 2012). Gases of deep origin can escape toward the earth's surface along preferential pathways such as fractures and crustal faults.…”