Abstract-Streamer characteristics have been experimentally and numerically analyzed for pulsed-corona discharge (PCD) and dielectric-barrier discharge (DBD) to find out how the discharge methods determine them and how they, in turn, affect the generation of radicals in flue gases. Experiments have been performed and compared for decomposition of a nitrogen oxide (NO) using PCD and DBD, and the electric field and average electron energy in the streamer are measured in each discharge by using line ratio Index Terms-Dielectric barrier discharge (DBD), nitrogen oxide (NO) decomposition, numerical modeling, optical emission spectroscopy, pulsed corona discharge (PCD), streamer characteristics.