Direkte Synthese und Trennung diastereomerer Phosphan‐Mangan‐Komplexe

Optically Active Transition Metal Complexes, XXXIV (+)579‐ and (‐)579‐(‐C5H5)Mo(CO) (NO)[P(C6H5)2N(CH3)CH(CH3)(C6H5)]

“…The optically active amino phosphine ( + ) (C H ) PN(CH3)CH(CH3)(C6H5), abbreviated with P02R*, can be prepared in two steps starting from S-(-) H2NCH(CHJ)(C6H5) 516). PP12R* has been used as a resolving agent in the preparation of optically active manganese and iron complexes [5][6][7][8] We succeeded in separating the two diastereoisomers by preparative liquid chromatography at 2 Merck columns (type B) with beneene/hexane 1:3. Two well separated red bands appeared; band one contained (-)I, band two (+)I.…”