Directional assist (0 1 0) plane growth in LiMnPO4 prepared by solvothermal method with polyols to enhance electrochemical performance

Xie, Qian; Jin, Zhu; Wang, Chengyun; Fang, Kaibin; Yang, Wei; Liu, Quanbing; Wang, Yali; Chen, Shengzhou

doi:10.1016/j.cjche.2020.10.027

Cited by 10 publications

(3 citation statements)

References 42 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Thus, reducing its crystal size along the b -axis can enhance the electrochemical performance. The strategy is also valid for the solid state method and solvothermal method. , Carbon coating is essential to boost the electrochemical activity of LiMnPO 4 . Some organic carbon sources such as glucose, sucrose, and cyclodextrin were mixed with LiMnPO 4 precursors or bare LiMnPO 4 and heated to form a carbon layer at high temperature.…”

Section: Discussion and Outlookmentioning

confidence: 99%

“…By crystal direction regulation, LiMnPO 4 crystals with shorter [010] direction can shorten diffusion distance of Li + ions through the bulk. 34 Low agglomeration and good dispersion facilitate infiltration of the electrolyte, which avoids Li + ions in the center suffering a long transfer distance. 35 The structure and electrochemical activity of LiMnPO 4 vary even when the same method is adopted albeit under the different control conditions.…”

Section: ■ Introductionmentioning

confidence: 99%

“…Li + ions migrate along the [010] crystal direction. By crystal direction regulation, LiMnPO 4 crystals with shorter [010] direction can shorten diffusion distance of Li + ions through the bulk . Low agglomeration and good dispersion facilitate infiltration of the electrolyte, which avoids Li + ions in the center suffering a long transfer distance …”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Effect of Synthesis Processes on the Microstructure and Electrochemical Properties of LiMnPO₄ Cathode Material

Han

Yang

et al. 2022

Ind. Eng. Chem. Res.

View full text Add to dashboard Cite

Section: Discussion and Outlookmentioning

confidence: 99%

Section: ■ Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Effect of Synthesis Processes on the Microstructure and Electrochemical Properties of LiMnPO₄ Cathode Material

Han

Yang

et al. 2022

Ind. Eng. Chem. Res.

View full text Add to dashboard Cite

Crystallography of Active Particles Defining Battery Electrochemistry

Morley,

George,

Hadler

et al. 2023

Advanced Energy Materials

View full text Add to dashboard Cite

Crystallographic features of battery active particles impose an inherent limitation on their electrochemical figures of merit namely capacity, roundtrip efficiency, longevity, safety, and recyclability. Therefore, crystallographic properties of these particles are increasingly measured not only to clarify the principal pathways by which they store and release charge but to realize the full potential of batteries. Here, state‐of‐the‐art advances in Li+, K+, and Na+ chemistries are reviewed to reiterate the links between crystallography variations and battery electrochemical trends. These manifest at different length scales and are accompanied by a multiplicity of processes such as doping, cation disorder, directional crystal growth and extra redox. In light of this, an emphasis is placed on the need for more accurate correlations between crystallographic structure and battery electrochemistry in order to harness crystallographic beneficiation into electrode material design and manufacture, translating into high‐performance and safe energy storage solutions.

show abstract

Engineering Crystal Orientation of Cathode for Advanced Lithium‐Ion Batteries: A Minireview

Zhu

Zhou

Yang

et al. 2022

The Chemical Record

View full text Add to dashboard Cite

Engineering crystal orientation has attracted widespread attention since it is related to the cyclability and rate performance of cathode materials for lithium‐ion batteries (LIBs). Regulating the crystal directional growth with optimal exposed crystal facets is an effective strategy to improve the performance of cathode materials, but still lacks sufficient attention in research field. Herein, we briefly introduce the characterization techniques and identification methods for crystal facets, then summarize and illuminate the major methods for regulating crystal orientation and their internal mechanism. Furthermore, the optimization strategies for layered‐, spinel‐, and olivine‐structure cathodes are discussed based on the characteristic of crystal structure, and the relationship between exposure of special crystal facets and lithium storage performance is deeply analyzed, which could guide the rational design of cathodes for LIBs.

show abstract

Directional assist (0 1 0) plane growth in LiMnPO4 prepared by solvothermal method with polyols to enhance electrochemical performance

Cited by 10 publications

References 42 publications

Effect of Synthesis Processes on the Microstructure and Electrochemical Properties of LiMnPO₄ Cathode Material

Effect of Synthesis Processes on the Microstructure and Electrochemical Properties of LiMnPO₄ Cathode Material

Crystallography of Active Particles Defining Battery Electrochemistry

Engineering Crystal Orientation of Cathode for Advanced Lithium‐Ion Batteries: A Minireview

Contact Info

Product

Resources

About

Directional assist (0 1 0) plane growth in LiMnPO4 prepared by solvothermal method with polyols to enhance electrochemical performance

Cited by 10 publications

References 42 publications

Effect of Synthesis Processes on the Microstructure and Electrochemical Properties of LiMnPO4 Cathode Material

Effect of Synthesis Processes on the Microstructure and Electrochemical Properties of LiMnPO4 Cathode Material

Crystallography of Active Particles Defining Battery Electrochemistry

Engineering Crystal Orientation of Cathode for Advanced Lithium‐Ion Batteries: A Minireview

Contact Info

Product

Resources

About

Effect of Synthesis Processes on the Microstructure and Electrochemical Properties of LiMnPO₄ Cathode Material

Effect of Synthesis Processes on the Microstructure and Electrochemical Properties of LiMnPO₄ Cathode Material