2011
DOI: 10.1039/c1gc15152e
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Direct transformation of cellulose into 5-hydroxymethyl-2-furfural using a combination of metal chlorides in imidazolium ionic liquid

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Cited by 117 publications
(68 citation statements)
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“…Ionic liquids have been used to prepare biomass catalytic degradation reactions of 5-HMF. As an aid for cellulose pyrolysis to prepare 5-HMF, ionic liquids obtain a relatively high yield and suppress many side reactions (Kim et al 2011). However, there are few reports on the kinetics of this reaction.…”
Section: Introductionmentioning
confidence: 99%
“…Ionic liquids have been used to prepare biomass catalytic degradation reactions of 5-HMF. As an aid for cellulose pyrolysis to prepare 5-HMF, ionic liquids obtain a relatively high yield and suppress many side reactions (Kim et al 2011). However, there are few reports on the kinetics of this reaction.…”
Section: Introductionmentioning
confidence: 99%
“…However, achieving a highly isolated 5-HMF yield from glucose has been a key challenge. The synthesis of 5-HMF from carbohydrates by a combination of different solvents [4,14,15], catalysts [16][17][18], and process conditions [19] has been broadly studied. However, a fundamental understanding and the knowledge base involved in the catalytic transformations of carbohydrates remain lacking in the literature.…”
Section: Introductionmentioning
confidence: 99%
“…12 In addition, homogeneous catalysts used together with a solid catalyst that contained Brønsted acid sites and/or Lewis acid sites were effective in the conversion of carbohydrates to HMF. [15][16][17][18][19][20] Zhang et al developed a hierarchically carbonaceous catalyst with Brønsted-Lewis acid sites, which was used to prepare HMF from cellulose in the ionic liquid 1-butyl-3-methylimidazolium chloride, and an HMF yield of 43.1% was achieved. 19 However, reactor corrosion, difficult downstream separation of the catalyst and the high cost of ionic liquids limited the application of the abovementioned methods for HMF production.…”
Section: -11mentioning
confidence: 99%