“…Comparable mechanochemically induced crystallisations of amorphous Mn 2 O 3 and SnO 2 were reported previously in our earlier studies [18,19].…”
Section: Methodssupporting
confidence: 87%
“…High energy milling of precursor powders leads to the formation of a nanoscale composite structure, which reacts during milling to form a mixture of separated nanocrystals of the desired phase within a soluble salt matrix, which is removed by water washing [16][17][18][19]. Herein, we report a facile mechanochemical synthesis of nanostructured VO 2 .…”
The high-energy milling of the V 2 O 5 -Na 2 SO 3 mixture in the range of 5 -100 min leads to a synthesis of monoclinic VO 2 . The starting and minimum (at 220 °C) values of electric resistance R of the 100 min milled and pressed VO 2 -Na 2 SO 4 mixture were 13.9 MΩ and 91.5 kΩ, respectively. The subsequent washing of the as-milled powder partially leads to the development of VO 2 nanostructures with tube-like, sheet-like and rod-like morphology, besides VO 2 (B) belt-like morphology, depending on the milling times.
“…Comparable mechanochemically induced crystallisations of amorphous Mn 2 O 3 and SnO 2 were reported previously in our earlier studies [18,19].…”
Section: Methodssupporting
confidence: 87%
“…High energy milling of precursor powders leads to the formation of a nanoscale composite structure, which reacts during milling to form a mixture of separated nanocrystals of the desired phase within a soluble salt matrix, which is removed by water washing [16][17][18][19]. Herein, we report a facile mechanochemical synthesis of nanostructured VO 2 .…”
The high-energy milling of the V 2 O 5 -Na 2 SO 3 mixture in the range of 5 -100 min leads to a synthesis of monoclinic VO 2 . The starting and minimum (at 220 °C) values of electric resistance R of the 100 min milled and pressed VO 2 -Na 2 SO 4 mixture were 13.9 MΩ and 91.5 kΩ, respectively. The subsequent washing of the as-milled powder partially leads to the development of VO 2 nanostructures with tube-like, sheet-like and rod-like morphology, besides VO 2 (B) belt-like morphology, depending on the milling times.
“…Manganese dioxide (MnO 2 ) can be used as a catalyst in oxidation-reduction reactions, as electrode materials in batteries, and in energy storage devices such as ultracapacitors [5]. The dimanganese trioxide phase (Mn 2 O 3 ) is quite attractive owing to its applications to produce soft magnetic materials [6] to catalyze the removal carbon monoxide and nitrogen oxide from waste gas [7,8] and in the catalytic combustion of methane [9]. The hausmannite phase, Mn 3 O 4 , has also been shown to possess electrochromic properties [10].…”
“…However, Mn 2 O 3 is also known to display different kinds of catalytic activity and also pseudo-capacitance, but it has been rather less investigated. [24][25][26][27][28][29][30] Herein we report a new way of preparing porous Mn 2 O 3 , starting from a 3D network of a coordination complex built up from a mixed-valent Mn II …”
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