“…Of particular interest are the studies that have exploited the stability of primary and early diagenetic calcite and aragonite in near-surface environments. Time periods and environments previously studied include Devonian and Pennsylvanian corals and diagenetic calcite (Smith and Farquhar, 1989;Smith et al, 1991Smith et al, , 1994, Ordovician limestones (DeWolf and Halliday, 1991), Permian marine limestones (Jones et al, 1995), Cambrian calcite concretions (Israelson et al, 1996), Paleozoic and Mesozoic soil calcite (Rasbury et al, 1997Wang et al, 1998), Cretaceous cave spar (Lundberg et al, 2000), calcite associated with Permian evaporite deposits (Becker et al, 2002), and late Paleozoic altered marine aragonite cement . The success of these studies has prompted others to investigate the U-Pb systematics of Cenozoic near-surface deposits including organic-rich peat (Rowe et al, 1997), speleothem calcite (Richards et al, 1998), secondary silica (Neymark et al, 2000(Neymark et al, , 2002, and coral aragonite (Getty et al, 2001).…”